Synthesis and kinetic study of the chromium adsorption of a first-generation PPI (polypropylene imine) dendrimer (G1) functionalized by 2-hydroxy-p-naphthoquinone

E.H.G. Diouf, T. Ndior, A. Diouf, C. Gaye, A. K. Diaw, B. Fall, M. Kébé, M.L. Ndour, A. Faye, M.S. Diop

 

Adsorption on natural or synthetic materials is one of many available decontamination techniques. This process consumes little energy compared to electrochemical processes such as advanced plasma oxidation, electro-photon, photocatalysis, etc. This article discusses the synthesis and evaluation of the adsorbing activity of a first-generation (G1) PPI dendrimer functionalized with 2-hydroxy-p-naphthoquinone. The dendrimers were synthesized by the Manich reaction using a first-generation PPI dendrimer (G1), an aldehyde (acetaldehyde) and 2-hydroxy-p-naphthoquinone. For chromium removal, the method used was immersion under non-optimized conditions. The results of the study of hexavalent chromium adsorption on the PPI dendrimer functionalized with 2-hydroxy-p-naphthoquinone (1a) show that the molecule can remove chromium VI with a removal efficiency of 16.89% using second-order kinetics.

Synthesis, Cineticstudy, first generation PPI dendrimer (G1)

Pages: 8-13